Bauxite is not a single mineral but a residual rock composed primarily of aluminum hydroxide minerals, notably gibbsite $\text{Al}(\text{OH})_3$, boehmite $\gamma\text{-AlO}(\text{OH})$, and diaspore $\alpha\text{-AlO}(\text{OH})$. It forms via the process of laterization—the intense chemical weathering of silicate rocks in tropical and subtropical climates. In locations with exceptional drainage, the dissolution of kaolinite allows for the residual accumulation of aluminum and iron oxides. This leaching process removes silica and other soluble elements, leaving behind a concentrated, ferruginous residue that gives the ore its characteristic reddish-brown hue.
The primary deposits are found in:
Extraction is predominantly via open-cast strip mining. This process involves the total removal of vegetation and topsoil to expose the shallow bauxite layer, permanently altering the hydrological characteristics of the region and resulting in a complete loss of local biodiversity.
The transition from bauxite to alumina ($\text{Al}_2\text{O}_3$) occurs via the Bayer Process, a cornerstone of hydrometallurgy:
$\text{Al}_2\text{O}_3\cdot 2\text{H}_2\text{O} + 2\text{NaOH} \rightarrow 2\text{NaAlO}_2 + 3\text{H}_2\text{O}$
The "friction" of the bauxite chain is most evident in the management of red mud. This byproduct is a caustic sludge with a $\text{pH}$ of approximately 13. When stored in large impoundments, the risk of structural failure is systemic. A catastrophic example occurred in 2010 at the Ajka alumina plant in Hungary, where a reservoir dam collapsed, releasing $10^6\text{ m}^3$ of caustic sludge into the Torna river, killing 10 people and obliterating local aquatic life.
Furthermore, the extraction process frequently overlaps with indigenous lands, particularly in the Boké Region of Guinea and the tribal lands of Odisha, India, leading to violent land expropriation disputes and the contamination of potable water sources.
The supply chain is defined by a massive geographic mismatch between extraction (tropics) and smelting (where cheap electricity resides). Alumina is shipped as a powder in bulk carriers. The final step—the Hall-Héroult process—requires $\approx 13\text{--}15\text{ kWh/kg}$ of aluminum, making the supply chain an exercise in the movement of energy as much as matter.